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  • First Direct Detection of HONO in the Reaction of Methylnitrite (CH
    We report on the development of a new environmental simulation chamber coupled with an in situ continuous wave cavity ring-down spectrometer operating in the near IR (∼1 5 μm) The first application reported in this paper dealt with the chemical mechanism of UV photolysis of methyl nitrite (CH3ONO) in air HONO has been detected for the first time and shown to be formed in the OH + CH3ONO
  • Kinetics of the Gas-Phase Reactions of OH Radicals, NO . . . - Springer
    OH Radical Reactions OH radicals were generated by the photolysis of methyl nitrite (CH3ONO) in air at wavelengths >300 nm (Atkinson et al , 1981), and NO was added to the re-actant mixtures to suppress the formation of O3 and hence of NO3 radicals 2,3-Dimethyl-2-butene was used as the reference compound for all the OH radical kinetic experiments
  • N O NO - egusphere. copernicus. org
    Hydroxyl radicals (OH) were generated by the photolysis of methyl nitrite (CH3ONO) in air in the presence of NO, following the reaction sequence below: CH3ONO + hν→ CH3O· + NO (R2)
  • Atmospheric Degradation of 4-Hydroxy 4-Methyl 2 . . . - ScienceDirect
    In both studies, OH radicals were generated by the photolysis of methyl nitrite (CH3ONO) in air at wavelengths O > 300 nm whereas 4H4M2P was formed from the oxidation of 1,3 butanediol and 2-methyl 2,4 pentanediol by OH radicals, respectively
  • First Direct Detection of HONO in the Reaction of Methylnitrite (CH3ONO . . .
    We report on the development of a new environmental simulation chamber coupled with an in situ continuous wave cavity ring-down spectrometer operating in the near IR (∼1 5 μm) The first application reported in this paper dealt with the chemical mechanism of UV photolysis of methyl nitrite (CH3ONO) in air HONO has been detected for the first time and shown to be formed in the OH + CH3ONO
  • Formation of acetone from the OH radical- and O3-initiated
    Bar, California NO by the photolysis of methyl nitrite (CH3ONO) in air at 2Alsoat Interdepartmental Graduate Program in Environmental Toxicology and Departmentof Environmental Sciences, University of wavelengths >300 nm [Atkinsonet al , 1981] California, Riverside
  • Kinetics of the Gas-Phase Reactions of OH and NO3 Radicals . . . - Springer
    OH radicals were generated by the photolysis of methyl nitrite (CH3ONO) in air at wavelengths >300 nm (Atkinson et al , 1981a), and NO was added to the Table I Rate constant ratios k1=k2 and rate constants k1 for the gas-phase reactions of the OH radical with monoterpene products at 296 2 K
  • Atmospheric and indoor chemistry of gas-phase indole, quinoline, and . . .
    The gas-phase chemistry of the nitrogen-containing organic compounds indole, quinoline and isoquinoline, which are present in environmental tobacco sm…
  • Atmospheric chemistry of the monoterpene reaction products nopinone . . .
    The 6400 liter all-Teflon chamber used for OHthe radical reactions wasequipped with woparallel banks of blacklamps Hydroxyl radicals were generated bythe photolysis of methyl nitrite (CH3ONO) in air atwavelengths >300 nm (Atkinson et aL, 1981, 1990b; Corchnoy andAtkin-son, 1990),
  • Rate constants for the gas-phase reactions of OH and NO
    Hydroxyl radicals were generated by the photolysis of methyl nitrite (CH3ONO) in air at wavelengths > 300 nm CH3ONO+hv~CH30+NO CHaO + 02 ~HCHO + HO2 HO2 + NO--OH + NO2 Nitric oxide was added to the reactant mixtures to avoid the formation of O3, and hence of NO3 radicals (see, for example, Atkinson et al , 1986b)





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